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bond length : ウィキペディア英語版
bond length
In molecular geometry, bond length or bond distance is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types, relatively independent of the rest of the molecule.
== Explanation ==
Bond length is related to bond order: when more electrons participate in bond formation the bond is shorter. Bond length is also inversely related to bond strength and the bond dissociation energy: all other things being equal, a stronger bond will be shorter. In a bond between two identical atoms, half the bond distance is equal to the covalent radius.
Bond lengths are measured in the solid phase by means of X-ray diffraction, or approximated in the gas phase by microwave spectroscopy. A bond between a given pair of atoms may vary between different molecules. For example the carbon to hydrogen bonds in methane are different from those in methyl chloride. It is however possible to make generalizations when the general structure is the same.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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